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Journal of Clinical Endocrinology & Metabolism, Vol 43, 696-699, Copyright © 1976 by Endocrine Society

ARTICLES

17-Deoxygenation: a new pathway of cortisol metabolism. Isolation of 17- deoxycortolonic acids

G Weiss, C Monder and HL Bradlow

The existence of a 17-deoxylation pathway in the metabolism of cortisol has been established by isolation of two 17-deoxy metabolites of cortisol. They have been identified as the 20alpha and 20beta-hydroxy isomers of 3alpha,20-dihydroxy, 11-oxo-5beta-pregnan-21-oic acids by comparison of the nuclear magnetic resonance spectra (nmr) and high resolution mass spectra of their methyl esters with authentic samples and confirmed by reverse isotope dilution.




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Copyright © 1976 by The Endocrine Society